Joshua Sharpes · Principal Engineer

Sharpes Process Engineering

Process design studies, plant equipment references, safety methodology, and instructional video content.

Sharpes Process Engineering is my independent practice for engineering problems worked past any single plant. This portfolio is what that looks like — full process design studies worked from first principles, equipment and safety references built to be actually used, and sixty-plus instructional videos on thermodynamics and process design worked through at the board.

2Full Design Projects
22Training Presentations
7Perry's Reference Notes
5Worked Problem Sets
72Instructional Videos

Equipment Design, Process Safety & Engineering History

25 original presentations organized by topic. Each deck links to an interactive viewer.

› Equipment Design & Heuristics 15 presentations
AbsorbersPPT

Six absorber types: agitated vessels (batch/continuous), bubble-cap towers (high residence time, low liquid rates), cooler absorbers (external/internal cooling for high heat of absorption), spray towers (droplet contact, entrainment tradeoffs), packed towers (most common, countercurrent gravity drainage), and venturi scrubbers (single-stage, high-solubility gases only).

Open Presentation ▶ Watch Video
Absorber HeuristicsPPT

36-slide design and evaluation guide — trayed vs packed selection (flow parameter Fp thresholds), structured vs random packing rules (tower diameter, liquid rate, pressure drop), packing factor Fp, flood point correlations (Sherwood-type), minimum/maximum liquid wetting rates, liquid distributor types and drip-point density, redistributor spacing, support plate weight limits, and three design methods: Kremser (lean gas), Edmister (multi-component), and HTU/NTU with mass transfer coefficient correlations.

Open Presentation
Compressor SelectionPPT

Compression basics (pressure ratio vs capacity tradeoff, heat capacity ratio k, polytropic efficiency). Four types: centrifugal (backward-curved impellers, surge at min flow, choke at max flow), reciprocating (high pressure ratio, interstage cooling), rotary (screw, lobe, sliding vane, liquid piston), and axial (low head, high flow, gas turbines). Vacuum service and driver selection.

Open Presentation ▶ Watch Video
Compressor Train SizingPPT

Compressor train sizing: pressure ratio and capacity tradeoffs across stages, interstage cooling placement, and polytropic vs isentropic efficiency calculations for driver power sizing.

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CondensersPPT

Film vs dropwise condensation mechanisms and heat transfer coefficient differences. Condensation complications from non-condensable vapor accumulation. Design heuristics for contact condensers (equilibrium temperature basis), dilute isothermal service, and temperature-range service. Source: Chemical Engineers' Condensed Encyclopedia of Process Equipment.

Open Presentation ▶ Watch Video
Cooling TowersPPT

Natural draft (hyperbolic tower, chimney effect, density differential), mechanical draft (induced vs forced fan, crossflow vs counterflow), atmospheric spray, and specialty types (deck-filled, coil-shed). Operating terminology: wet-bulb temperature, cycles of concentration, drift, blowdown, makeup water calculations, plume formation, and acceptance testing. Source: Encyclopedia of Process Equipment.

Open Presentation ▶ Watch Video
Flow MetersPPT

Nine flow meter types: Venturi, Dall (lower permanent pressure drop), orifice plate (sharp-edge contraction, straight-run requirements), flow nozzle (high Reynolds number), pitot tube, positive displacement (piston meters, batch/blending), mechanical (rotameters), magnetic (Faraday's law, conductive fluids), and ultrasonic/Doppler (suspended solids service). Comparison table and selection criteria.

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Heat ExchangersPPT

Three distinct analysis workflows — Design (sizing new equipment from heat duty and temperature requirements to meet performance targets), Rating (predicting actual duty and pressure drop for existing equipment at off-design operating conditions), and Simulation (what-if studies, fouling buildup, startup/shutdown transients, sensitivity analysis across process changes).

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Shell and Tube Exchanger Design HeuristicsPPT

Temperature crossover management: single 1-1 pass (TC-proof but velocity-limited), multi-pass shell/tube configurations, and the conditions under which each approach applies. Shell-side vs tube-side fluid assignment rules: corrosive fluids in tubes (easier bundle replacement), dirty fluids in tubes (easier cleaning), condensing fluids in shell, high-pressure service in tubes (thinner vessel walls).

Open Presentation
Heat Exchanger FoulingPPT

Fouling mechanisms from Bott's Fouling of Heat Exchangers: particulate, crystallization/scaling (supersaturation, nucleation, normal vs. inverse solubility), corrosion, and chemical-reaction fouling, each with where it deposits, upstream prevention, and in-exchanger mitigation. Type-independent best practice (clean upstream service, separation ahead of the exchanger), deposit-growth trends (asymptotic, linear, falling-rate), and the Kern-Seaton asymptotic model Rf(t) = Rf*(1 − e−t/τ).

Open Presentation
CorrosionPPT

Corrosion from Perry's 9th Edition: electrochemistry, Pourbaix passivation diagrams, and polarization; localized corrosion (pitting, crevice, intergranular, galvanic, dealloying); environmentally assisted cracking (SCC, hydrogen embrittlement, liquid-metal embrittlement, corrosion fatigue); high-temperature gaseous corrosion (oxidation, carburization, sulfidation, halogens, nitridation, molten salts); and prevention practice for heat exchangers, towers, tanks, and piping, plus process-environment changes (passivation promotion, deaeration, scale enhancers).

Open Presentation
Storage VesselsPPT

Fixed-roof tanks (flat, conical, dome roof types), floating-roof tanks (pontoon buoyancy design, rim seals for low-boiling liquids, solar boiling prevention), conservation gas holders (variable volume at fixed pressure), and open-top tanks. Tank appliances: conservation vents, hatches, mixers, and their leak exposure. Source: Encyclopedia of Process Equipment.

Open Presentation ▶ Watch Video
Vertical Gas-Liquid SeparatorsPPT

Souders-Brown K factor (0.15–0.25 ft/s, decreasing at higher pressure) for vessel diameter sizing, height heuristic (H = 4×D baseline), liquid residence time by service (1–3 min clean hydrocarbon, 3–5 min moderate viscosity, 5–10 min dirty/foaming), mist extractor knockdown of entrained liquid, nozzle placement, and independent PIC (vapor)/LIC (liquid) control loops — must not be coupled to avoid interaction.

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Rules of ThumbPPT

Cross-equipment heuristics for fast first-pass checks: control valve authority (50–60% of system pressure drop for adequate control), PSV relief scenario selection under API 521 (including high-pressure-into-low-pressure breakthrough evaluation), pump best-efficiency-point tradeoffs (65–95% BEP range, reliability vs. energy consumption), and heat exchanger simulation methods (Dittus-Boelter, Bell-Delaware).

Open Presentation
Equilibria Approach SelectionPPT

Decision workflow for selecting a thermodynamic property method — Classical (gamma-phi), EOS (phi-phi), or Hybrid — gated on electrolyte presence, liquid-phase ideality (UNIFAC, Kamlet-Taft/Gutmann DN-AN, and Flory-Huggins fallbacks), and pressure vs ~10 bar. Stress-tested and validated against 11 real petrochemical process families from the Meyers Handbook, with per-bucket case-study results and characterization of which systems typically land in each approach.

Open Presentation
› Process Safety 9 presentations
Engineering Protection LayersPPT

From GFEDPS Chapter 7 — protection layer hierarchy (ISD → control → active mitigation), electrical area classification (ANSI/NFPA 70 Class I/II/III), SIS/SIL/IPL definitions (IEC 61511), pressure relieving systems, equipment isolation and blowdown, flare systems (API 521), vapor incineration (40 CFR), fire protection modes (HC burning, pyrophoric material), deflagration/detonation arresters, explosion suppression, and dike containment design.

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Inherently Safer DesignPPT

Safeguarding hierarchy (passive → active, decreasing reliability with increasing complexity). ISD strategies applied unit-by-unit: tank reactors (runaway prevention), continuous reactors, mass transfer columns, heat exchangers (tube leak prevention: thermal difference reduction, heat throttle), dryers (combustible dust, multicomponent LEL reduction), pumps (deadheading, cavitation), compressors, fired equipment, piping (40% of LOC incidents, ASME B.31), and utilities.

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HAZOP MethodologyPPT

27-slide study guide from Crawley & Tyler's Guide to Best Practice — ICI origins and 6-stage Hazard Study workflow, guideword/parameter matrix construction, node definition, cause-consequence-safeguard chain evaluation, risk matrix (qualitative), HAZOP team assembly (leader, scribe, discipline members), meeting structure, recording format (dedicated PHA software, sectioned tables), auditing, and training pathways. Handoff to LOPA and MOC covered.

Open Presentation
PSV Relief Scenarios — API 521PPT

API 521 overpressure scenario identification (closed outlets, cooling/reflux failure, volatile material ingress, overfilling, control failure, fires, tube rupture, utility failure, hydraulic expansion, chemical reactions per DIERS methodology) → governing scenario selection. Vacuum relief evaluation, vapor depressuring design (vessel rupture pressure, failure time, brittle failure temperature), and operator response time thresholds.

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Process Safety InformationPPT

From GFEDPS Chapter 8 — three PSI categories under OSHA PSM: Chemical Hazards (MSDS, reactivity, toxicity, explosive limits, heat of combustion), Process Technology (C&E matrix, P&IDs, SIS lifecycle documentation, PHA findings), and Process Equipment (equipment specs, drawings, electrical diagrams, structural analysis). Distinction between design basis, engineering design package, and EDMS-managed equipment files.

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Apollo Root Cause MethodologyPPT

Four-step Apollo RCA — Step 1: Problem definition (what/when/significance/impact), Step 2: Reality chart construction (causal chains with action and condition causes; three evidence types: sensed, inferred, testimonial), Step 3: Effective solutions (criteria: prevent recurrence, within control, meets organizational goals; creative thinking methods), Step 4: Implement and track with profitability review to inform future decisions.

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What Went WrongPPT

26 incident case studies from Kletz's "What Went Wrong" — compressed air oil deposits, aluminum dust explosion (Huntington IN 2003), furnace tube rupture, amine tower BLEVE (17 dead), Longford explosion (Exxon Australia 1998), Feyzin tank BLEVE (TotalEnergies 1966), nitrogen asphyxiation (Union Carbide 1998), HF Puget Sound spill, floating roof tank fire (Wales 1983), water hammer rupture (BP UK 2000), static electricity in powder, check valve backflow, and others with root cause lessons.

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Hazard Evaluation ProceduresPPT

Chapter-by-chapter walkthrough of CCPS Guidelines for Hazard Evaluation Procedures (76 slides): incident anatomy and safeguard purpose; study preparation (scope, team, scheduling); hazard identification (inherent hazards, interaction matrices, worst-case consequence); non-scenario methods (PreHA, Safety Review, Relative Ranking, Checklist); scenario methods (What-If, What-If/Checklist, HAZOP, FMEA, Fault Tree with minimum cut sets, Event Tree, Cause-Consequence); the Chapter 6 selection flowchart and MOC hazard reviews; risk-based safeguard adequacy through LOPA; follow-up and action-item resolution; and special applications (procedures, programmable systems, reactivity, human factors, facility siting).

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Layer of Protection AnalysisPPT

LOPA methodology as a semi-quantitative follow-on to HAZOP — initiating event frequency estimation, independent protection layer (IPL) identification and credit rules, enabling conditions and conditional modifiers, and comparison of mitigated event likelihood against corporate risk criteria to determine required SIL.

Open Presentation
› Engineering History 1 presentation
ChemE LegendsPPT

Profiles of fifty-nine engineers and scientists behind the methods process engineers use daily: Henry Kister (distillation, Fluor), Ernest Ludwig (Applied Process Design), Alois Kremser and Wayne Edmister (absorption), Max Peters and Ronald West (Plant Design and Economics), Donald Kern (process heat transfer), Igor Karassik (Pump Handbook), Joseph Leung (relief sizing), Thomas Bott and James Knudsen (fouling), Jürgen Gmehling (UNIFAC), Merrel Fenske, A.J.V. Underwood, Mott Souders, Sabri Ergun, Allan Colburn, Thomas Chilton, Lawrence Evans (Aspen Technology), and more, from Bernoulli and Stokes to present-day Perry's section editors.

Open Presentation

Interactive Calculations

Live calculators built from API standards and first principles. Adjust any slider and results update instantly.

Units
applies to every calculator below
› API 521 §5.5.10 — HEM Tailpipe Backpressure Calculator Method & code USC units

Homogeneous equilibrium model (Leung 1986) · USC units · Solves for upstream pressure p₁ · Built-up backpressure check per API 521 7th Ed.

Flow and fluid
Relief load W (lb/h) 10,000
Component
Vapor fraction x 0.30
Ref. pressure pR (psia) 50
Ref. density ρR (lb/ft³) 20.0
Flash pressure p (psia) 15
Flash density ρ (lb/ft³) 15.0

Pipe geometry
Pipe ID (in) 4.0 in
Equiv. length L (ft) 100 ft
Fanning friction f 0.005
Pipe material
Exit pressure p₂ (psia) 15.0

PRV type
Set pressure (psig) 150 psig
Choking
—
—
Backpressure
—
—
Upstream p₁
—
—
Mass flux G
—
lb/h·in²
Omega ω
—
Critical pressure pc
—
psia
Flow choked?
—
Solved p₁
—
psia
ΔP tailpipe
—
psi
Exit velocity
—
ft/s
Built-up BP
—
% of set
Step-by-step detail

API 521 7th Ed. (Jun 2020) §5.5.10 · Homogeneous equilibrium model (Leung 1986) · USC units · For engineering study use only

› Centrifugal Pump Sizing — Case Study Tool Method & code USC/SI toggle

Centrifugal Pump Sizing — Case Study Tool

Runs input duty conditions through the workflow in Centrifugal Pump Sizing.pptx (single-stage, radial/mixed-flow only). Fluid properties come from a precomputed thermo table (11 pure compounds) embedded in this file — fully self-contained, no backend, drops straight into a static site. Every slider is bounded per sizing_tool_parameter_limits.md; less-frequently-changed constants are fixed in code rather than exposed here.
Units controlled by the site-wide US/SI toggle at the top of the Process Engineering Tools section above.

Fluid

Duty conditions

Collector type (volute, +vaned diffuser above ~150 ft/s tip speed) is determined by the workflow, not selected here — see the Collector panel below.
Vendor documents
Downloads use this panel's most recently computed results (run the calculator with your duty conditions first).
Download Slides (.pptx)
Screening — single-stage centrifugal (radial/mixed-flow) range
Specific speed, Ns (US)
Dimensionless Ωs
Fig. 12 range: 0.2 – 1.6
Impeller classification
Speed, NPSH & cavitation slides 3–7, Fig. 25
PolesN (rpm)NssStatus
Selected N / U₂
Required NPSHr (spec limit)
Nss —
Impeller & collector geometry slides 7, 9–17
Shaft radius rs (from torque)
Eye flow coeff. φₑ
Eye diameter De
Exit diameter D₂
Exit width b₂
Blade angle β₂ᵦ
Blade count nb
Base circle D₃ / throat At
Predicted performance curve — trim-diameter family slide 21
Family generated via standard affinity-law scaling (Q∝D, H∝D²) of the sized (100%) curve — the same method vendor curve sheets use to show a trim range off one tested casing. Blade angle + BEP-locked slip velocity held fixed across flow; dashed segment near shutoff is interpolated, not modeled. Each trim is a scaled copy of the same underlying shape (affinity laws don't independently re-derive a curve per diameter), so all trims look near-linear together at low-to-mid Ωₛ — expected physics per Karassik (rise-to-shutoff curvature grows with specific speed; see the gap note below), not a rendering bug.
Axial thrust & balancing slides 24–25
Net axial thrust T (K=0.6 corrected)
Impeller-OD pressure p₂
Shutoff head (≈0.585·U₂²/g)
Final balanced performance
Overall η (balanced) — final
BHP (balanced) — final
Δ vs. first pass
First-pass numbers (pre-balancing) — reference only
ηHY
ηm
ηv
Overall η (first pass)
BHP (first pass)
BHP cross-check (Jekat)
Assumptions used & known gaps
Fixed internal constants (see sizing_tool_parameter_limits.md)
Not implemented (deck doesn't yet give a closed form) — case-study findings
Self-contained: no external scripts, no CDN, no network calls. Fluid properties are a precomputed thermo lookup table baked in at build time. Formulas trace to slide numbers in Centrifugal Pump Sizing.pptx; where the deck only gives a chart/qualitative guidance, a documented approximation is used and flagged below. CFD verification (slides 22–23) is out of scope for a closed-form calculator. Q/H slider bounds and the two corner flags are an approximate reading of Pump Selection Guidelines.png (Fig. 10-24-style pump coverage chart), not a pixel digitization.
› Flow Meter Selector — Process Conditions → Recommended Meter Type Method & code 10 meter types

Rule-based selection guide built from the criteria in the Flow Meters presentation — every recommendation below cites the specific slide fact behind it, not a generic scoring model. Set your process conditions; the meter list re-ranks live.

Phase & Fluid Properties
Phase
Conductivity (liquids)
Viscosity
Solids & Multiphase
Solids / bubbles
Two-phase flow present
Corrosive / abrasive service
Process Conditions
Process pressure
Temperature
High velocity / Re, or capacity increase without re-piping
Large duct/pipe — need velocity traverse
Priorities & Service
Minimize permanent pressure drop
Accuracy requirement
Service type
Flow rate

Selection logic derived from Flow Meters presentation content (Venturi, Dall, orifice plate, flow nozzle, Pitot tube, positive displacement, rotameter, turbine, magnetic, ultrasonic/Doppler) · For engineering study use only

› Compressor Train Sizing Calculator — Type, Efficiency, Power & Stage-Count Optimizer Method & code N = 1-6 stages

Sizes a multi-stage compressor train (equal pressure ratio per stage, full intercooling back to suction temperature) from Compressor Selection/Sizing methodology — auto-suggests type and efficiency method from your process conditions, then sweeps N = 1-6 stages to recommend the economically optimal stage count (Seider Ch. 16.5 equipment costing + Peters & Timmerhaus payback screen). Change any input and every result recomputes live. See the Compressor Selection, Compressor Train Sizing, and Perry's Compressors presentations for the underlying method.

Critical Inputs
Gas
Manual MW (lb/lbmol)
Manual k = Cp/Cv
Compressibility factor, Z
Suction temperature, T1 (°F)
Suction pressure, P1 (psia)
Final discharge pressure, P2 (psia)
Mass flow rate, ṁ (lb/hr)
N_stages (1-6, drives results panel)
Type & Efficiency (auto-computed — override anytime)
Auto-suggested type—
Type override
Effective method—
Method override
Manual ηp
Casey & Robinson Eq. 17 — f1/f2 come from their Appendix 1 equations 23/24, not in this project's source decks. Enter vendor/external values.
η1 (reference efficiency)
Bref
fref
f1
f2
Balje chart itself isn't in the source decks — Ns/Ds are computed here, but ηc must be read off the chart elsewhere and entered manually.
Shaft speed, N (rpm)
Impeller diameter, D (ft)
ηc (read from Balje chart)
Computed Ns / Ds—
Economics
Operating hours/year
Electricity cost ($/kWh)
Risk level (Table 8-1, P&T)
mar (midpoint of risk band)—
N, evaluation period (yr)
Cost & Sizing Basis (Seider Ch. 16.5 — real defaults, rarely changed)
CEPCI Year
Manual CEPCI
Effective CEPCI—
Compressor driver
Compressor material
Compressor bare-module factor
Intercooler head type
Intercooler shell/tube material
Intercooler tube length (ft)
Overall U (Btu/hr·ft²·°F)
Cooling water in (°F)
Cooling water out (°F)
Intercooler bare-module factor
Combined tax rate
Results at N = 3 stage(s)
Inlet flow, Q
—
ACFM
Adiabatic head, H_ad
—
ft
Effective type
—
Selected ηp
—
Polytropic exponent, n
—
Discharge temp, Tout
—
°F
Tallow flag
—
Train power
—
hp
Per-stage power
—
hp
—
—
Show N = 1-6 stage-count sweep (Stage-Count Optimizer detail)
ηp is held constant across this sweep at the Selected ηp above (computed once, at your current N_stages) — a documented Class-5 (±30-50%) screening simplification, not re-derived per row.
Nr_stageH_ad (ft)TypeTout (°F) Tallow flagTrain hpTCI ($)Incr. PBP (yr)Passes?
Carries every input/override above into "Compressor Train Sizing.xlsx" — formulas stay live, so Sheets 2-6 recalculate in Excel from what you typed here.
Known simplifications / gaps (carried from the source workbook)
  • Fig. 10-64 type-selection boundaries are eyeballed from a chart image, not precisely digitized — cross-check borderline operating points against the reference chart.
  • Gas library MW/k are approximate ideal-gas values near ambient — use Custom/Manual Entry for mixtures or non-ideal conditions.
  • Scale-Up method needs external Casey & Robinson friction-factor data not present in this project's source decks.
  • Balje method's chart itself isn't available — ηc must come from an external chart reading.
  • Seider Ch. 16.5 only gives compressor cost equations for Centrifugal, Reciprocating, Screw — every other type shows "n/a - outside Seider correlation coverage," not a fabricated fit.
  • CEPCI defaults to 567 (no escalation) unless you pick a real year.
  • Combined tax rate defaults to 21% flat federal (no state) — editable above.
  • Depreciation life for the after-tax cash flow reuses the evaluation period N, not a separately specified MACRS schedule.
  • The Stage-Count Optimizer holds ηp constant across the N=1-6 sweep — a documented Class-5 (±30-50%) screening simplification, not per-row-accurate.
  • Intercooler sizing uses an assumed overall U and a standard 90/120°F cooling-water basis to back into an area for costing — not a full thermal/mechanical HX design.

Equal pressure ratio/stage, full intercool to T1 · Seider, Seader, Lewin & Widagdo Ch. 16.5 equipment costing · Peters & Timmerhaus Eq. 8-2a/8-2c payback screen · For engineering study use only

› Jacketed / Packed-Bed Reactor Scale-Up Calculator Method & code lab → pilot

Scales a jacketed or packed-bed PFR exothermic reaction from lab to pilot diameter, holding target conversion and L/D fixed while sweeping tube diameter D. Every reaction has its own binding scale-up constraint — cooling surface/volume, thermal stability, or pressure drop — derived from first principles and verified public literature (see reference panel), not vendor/proprietary numbers. Pick a reaction and L/D; every result and chart recomputes instantly from a precomputed sweep (Python/SciPy, baked in at build time — no live solver in the browser).

Reaction Scheme
NO₂ + 3 H H Pd cat. NH₂ + 2 O H H
Simplified skeletal structures — illustrative, not to bond-angle/3D scale.
Reaction
Reaction
—
Geometry
Reactor L/D ratio 100
Bounded to the L/D range validated against the underlying reactor model (see gaps below).
Fixed, Reaction-Coupled Basis
Selecting a reaction locks in its whole validated bundle — feed composition, coolant, target conversion, feed temperature, and reactor type (empty-tube jacketed for Aniline; packed-bed for Cumene) — not exposed as separate sliders, matching this tool's minimal-input design.
Recommended Design Point at L/D = 100
Recommended tube diameter
—
mm
Throughput at that diameter
—
kg/h
—
Why this diameter — the limits behind the recommendation
Peak reactor temperature vs. tube diameter
Exit conversion vs. tube diameter
Throughput vs. tube diameter
Reference Data — — (fixed, not user-editable)
Known simplifications / gaps
    › EO Runaway Relief Calculator — Loss of Mixing (EG → PEG) Method & code preliminary

    KOH-catalyzed ethoxylation of ethylene glycol to PEG · local EO pocket at the feed point · tempered venting at relieving pressure · API 520 / Leung ω sizing · SI units, pressures bar absolute · preliminary — see basis and limitations below

    Failure mode
    Full scenario description
    ESD response time (s) 15 s
    EO keeps entering the stagnant liquid at the dip-leg until the ESD valve closes. Pocket EO = feed rate × response time.

    Reactor and product
    Reactor volume (m³) 6.0 m³
    Product (PEG grade)
    Batch progress (%) 50 %

    Operating conditions
    Temperature (°C) 140 °C
    Operating pressure (bar a) 3.62
    MAWP = PSV set (bar a) 4.45
    EO feed rate (kg/min) 16.0
    Advanced assumptions
    KOH (wt% of final batch) 0.30 %
    Kinetic multiplier (×k11) 1.0
    Dip-leg pipe ID (mm) 40.9 mm
    Sets the pocket's cross-section, and the submerged discharge — Chiu thesis: the dip-leg's bent section "extends to below the bottom-most impeller", so the pocket forms in bulk liquid near the vessel bottom, not at the vapor space. Default sized to feed rate at a design velocity of 0.255 m/s — back-derived from Chiu thesis Table 7.2, where both real reactor tiers (40.9 mm ID/18 kg/min and 52.5 mm ID/28 kg/min) land within 4% of this same velocity at their peak feed. Recomputes with feed rate and feed temperature; override here if a real pipe ID is known.
    Stagnant zone length (× pipe ID) 15×
    How far down the dip-leg the submerged dead zone extends, in pipe diameters. No source for this multiplier — pure assumption; pocket carrier mass = zone volume × liquid density (shown below), not a fraction of the whole batch.
    Valve-to-nozzle line length (m) 2.0 m
    EO already standing in the line between the ESD valve and the nozzle keeps draining into the pocket after the valve closes, on top of feed×response-time — only applies to failure modes where the valve actually closes (A, C). This length is set by isolation-valve maintenance clearance (no bypass is installed for this CV, so it's a straight run, not a bypass loop), not by the dispersion physics that size the stagnant zone above; no source for a typical value here.
    Pocket→bulk blend time (s) 60 s
    Time constant for the pocket to homogenize into the bulk after the mixer restarts (turbulent blend time) — not the failure duration set above. No source; assumption. A fully physical (heat-transfer-coefficient × contact-area) version would need the polyether's liquid viscosity and thermal conductivity, which aren't sourced yet — see basis notes.
    EO feed temperature (°C) 18 °C
    Chiu thesis §7.3.1: EO header temperature is "almost always under 20 °C (15–20 °C)"; up to 30 °C possible for the first slug on a hot day.
    Max fill at 100 % (vol %) 80 %
    Chiu thesis Table 3.1: the 2-litre kinetics autoclave runs at 1600 mL of 2000 mL max working volume = 80 %. Used as the sourced default; no production-vessel fill % found in our sources.
    N₂ pad at 25 °C (bar a) 1.01
    Coolant ΔT at normal duty (K) 30 K
    Accumulation over set (%) 10 %
    Discharge coeff. Kd 0.85
    Rupture disk upstream
    Vapor-phase EO decomposition
    Relief demand
    —
    —
    Decomposition risk
    —
    —
    Normal-operation check
    —
    —
    Pocket EO mass
    —
    kg (= feed × time)
    Local EO in pocket
    —
    wt % at restart
    Peak relieving rate W
    —
    kg/s
    Time of peak
    —
    s after mixer restart
    Total vented mass
    —
    kg
    Peak pressure
    —
    bar a
    Peak bulk temperature
    —
    °C
    Peak pocket temperature
    —
    °C
    Required orifice
    —
    Relieving rate and vessel response after mixer restart
    Required relieving rate W (kg/s) — homogeneous vent, holding P at relieving pressure
    Vessel pressure (bar a)
    Vessel PSet = MAWPRelieving P
    Temperatures (°C)
    Bulk liquidEO pocketDecomposition onset (pure EO, APTAC ≈ 205 °C)
    Relief device sizing (API 520 two-phase, Leung ω)
    Alternatives — valve type, rupture disk, effluent destination
      Step-by-step detail
      Basis and limitations
        › Pressure Vessel Cost vs. Diameter — ASME VIII-1 Wall, MAWP/MAWT, Material Screen, Itemized Installation Method & code FEL-1

        Sizes a pressure vessel's wall from ASME Section VIII-1 (UG-27, allowable stress from ASME II-D 2013), back-calculates MAWP and MAWT, screens materials of construction for the service (corrosion allowance vs. cracking mechanisms), and builds purchase + itemized installation cost (Seider Ch. 16, Guthrie line items) across a diameter sweep. A second tab applies the same engine to the Haber-Bosch synthesis-loop pressure trade-off: equilibrium conversion and recycle vs. converter/separator wall and compression.

        Inputs

        Geometry

        Process conditions

        Material of construction

        Off = Seider convention (CA added on top of min. thickness). On = Coulson §13.4.8 convention (min. thickness includes CA). Pressure thickness is never counted as CA.

        Installed cost vs. diameter

        Material comparison vs. diameter

        Solid line = acceptable for the service. Materials excluded by the service screen are not plotted. ● = cheapest at each D.

        Mechanical design at D =

          Cost build-up (itemized installation)

          Material screen at this diameter

          Corrosion rates in the service table are illustrative FEL-1 screening values (order-of-magnitude, typical handbook ranges), not from a corrosion database. Rating per Perry's 9th Table 25-3: ✓ < 2 mpy, △ 2–16 mpy, ✗ ≥ 16 mpy. Localized-attack / cracking mechanisms exclude the material outright; a corrosion allowance cannot fix them.

          Loop basis

          Anchored on Design\Ammonia Process (400 MTPD, makeup 578 mol/s from 25 bar, V-501 at −10 °C, K = 0.107 m/s knock-out sizing). Design case: 150 bar loop, recycle ratio 5 (Ammonia Plant Memoir, as published on the portfolio site).

          Compressor drive & energy

          Converter shell: SA-387 22 Cl.2 (2¼Cr-1Mo, hot hydrogen). Separator: SA-516-70. Both use the Vessel tab's engine (thickness → weight → Seider cost → itemized installation). Compressors: Seider Eq. 16.36 centrifugal with drive factor FD (motor 1.00, steam turbine 1.15), installed ×2.15.

          Annualized cost vs. loop pressure

          Loop response vs. pressure

          Pressure sweep table

          Calculation chain

          1. Design conditions (Seider §16.5): Pd = 10 psig if Po ≤ 5 psig; exp{0.60608 + 0.91615 ln Po + 0.0015655 (ln Po)²} for 5–1000 psig; 1.1·Po above 1000 psig. Td = To + 50 °F.
          2. Allowable stress S(Td): ASME II-D 2013 Table 1A/1B, Section VIII-1 column, linear interpolation. Local file asme_iid_stress.json (page refs per material). Blank above the material's VIII-1 temperature limit.
          3. Pressure thickness: UG-27 tp = PdR/(SE − 0.6Pd) (= Seider 16.60); Appendix 1-2 thick-wall form t = R(eP/SE − 1) when P > 0.385SE. E = 0.85 (spot RT) up to 1.25 in, 1.0 above (Seider).
          4. Vertical wind/seismic (Seider 16.62): tw = 0.22(Do+18)L²/(S Do²); tv = tp + tw/2 (average of top and bottom).
          5. Minimum thickness (Seider): ¼ in to 4 ft, 5/16 to 6 ft, 3/8 to 8 ft, 7/16 to 10 ft, ½ in to 12 ft; +1/16 in per 2 ft above 12 ft (extrapolated).
          6. Corrosion allowance = rate × design life (min 1/16 in). Credit toggle: off → t = max(tp, tmin) + CA (Seider); on → t = max(tp + CA, tmin) (Coulson, minimum includes CA). Round up to plate: 1/16 in steps to ½ in, 1/8 in to 2 in, ¼ in above.
          7. MAWP: UG-27 inverted on the corroded thickness (tnom − CA) at Td. MAWT: highest temperature at which S(T) still gives MAWP ≥ Pd on the corroded wall, capped at the VIII-1 limit. Corrosion life = (tnom − tp)/rate: all metal above the pressure requirement, including min-thickness and plate-rounding surplus.
          8. Weight (Seider 16.59): W = π(Di+t)(L+0.8Di)t·ρ with ρ = 0.284 lb/in³ (Seider's cost basis; heads same thickness as shell). Actual shipping mass uses the material's own density.
          9. Purchase cost (Seider 16.52–16.56, CE 567): CP = FMCV + CPL. Vertical CV = exp{7.1390 + 0.18255 lnW + 0.02297(lnW)²}, CPL = 410D0.7396L0.70684; horizontal CV = exp{5.6336 + 0.4599 lnW + 0.00582(lnW)²}, CPL = 2275D0.2094. FM from Seider Table 16.26.
          10. Installation, itemized: Guthrie line items (Seider Table 16.10: piping 0.456, concrete 0.051, steel 0.031, instruments 0.102, electrical 0.020, insulation 0.049, paint 0.005, erection 0.554, setting 0.076, freight 0.080, overhead 0.571, engineering 0.296 × CP; sum 2.291) scaled so they total the vessel bare-module factor FBM − 1 (Seider Table 16.11: vertical 4.16, horizontal 3.05). Installation is charged on the carbon-steel purchase cost (Seider Eq. 16.12). Assumption: vessel line items share the heat-exchanger split.
          11. Contingency + fee: 15% + 3% (Seider, on direct permanent investment ≈ bare-module cost for one item).
          12. Cost year: escalated CE 567 → 800 (single fixed index; relative comparisons are the point of this tool).

          Service screening

          Follows the Plant Resources\Materials of Construction methodology (per-mechanism, UNS-named, Perry's 9th Table 25-3 ratings, FEL-1 screening only). Corrosion rates are illustrative placeholders pending a sourced corrosion database (NACE/MTI data are not on disk). Hot-hydrogen limits are an approximate reading of API 941 Nelson curves at high H₂ partial pressure. Verify before use.

          Haber-Bosch case study

          Equilibrium: Gillespie-Beattie Kp (atm⁻¹, ½N₂ + 3/2H₂ ⇌ NH₃), ideal gas (fugacity corrections neglected, which understates conversion at high P), 3:1 H₂:N₂ plus inerts. Per-pass outlet NH₃ = inlet + approach × (equilibrium − inlet). Inlet NH₃ = NH₃ vapour pressure at the separator T ÷ loop P. Loop flow F = ξ(1+yout)/(yout − yin). Converter catalyst volume = converter inlet flow at STP ÷ GHSV (standard-condition space velocity, as industrial converters are rated); vessel volume = 1.3 × catalyst. Because the catalyst volume does not shrink with pressure, wall metal (∝ P × V) and converter capital rise with loop pressure. A residence time at actual conditions would make V ∝ 1/P and cancel that effect exactly (pV = nRT). Separator: Souders-Brown K = 0.107 m/s (Ammonia Process knock-out basis), L/D 3.5. Makeup compressor: intercooled (40 °C), equal ratios ≤ 3 per stage, ideal-gas polytropic; circulator lifts loop flow by the loop ΔP. Compressor cost: Seider Eq. 16.36 centrifugal CB = exp{9.1553 + 0.63 ln PC} (hp, CE 567, includes motor) × FD (1.15 for a steam-turbine drive, Eq. 16.35), installed ×2.15. Compression energy: electric drive = grid price ÷ 0.95 motor efficiency; steam-turbine drive = steam rate × blended steam value, where the blend is the share of turbine steam raised from recovered reformer convection-section / loop WHB heat (default $0.53/t, its boiler-feed-water cost, i.e. surplus heat with no other use) vs make-up steam that must be fired or bought (default $17.60/t, Seider Table 17.1, 450 psig). Default steam rate 3.45 kg/kWh: condensing turbine, 105 bar / 510 °C (Ammonia Process Memoir HP header) to 0.10 bar, 80% isentropic (IAPWS-95); a back-pressure turbine to 4.5 bar needs ≈ 5.9 kg/kWh. Integration only pays when the steam is genuinely surplus: if it could otherwise run a turbo-generator, its value approaches the grid price and the steam drive saves little. The recovered-steam supply is not capped (no plant steam balance). Refrigeration duty is not included. Proof of concept: trends, not a design.

          Sources on disk

          • ASME II-D 2013 (Customary): Vessel Scale Up folder.
          • Seider, Seader, Lewin & Widagdo, Ch. 16: FEL Projects\Economics\Seider.pdf (PDF p.476–477, 500–503).
          • Coulson & Richardson Vol. 6 (Sinnott) §13.4.8: Textbooks (Level 1)\Process & Plant Design.
          • Meyers, Handbook for Petrochemical Production Processes: Textbooks (Level 1)\Process-Specific References. Preset conditions per chapter noted in the preset hint.

          Full Process Design Studies

          Two plant-scale design projects worked from first principles — mass and energy balances, equipment sizing, thermodynamic calculations, and process narrative written as a working engineering memoir.

          Ammonia Production Process

          Complete design study of an SMR-based ammonia synthesis loop. Covers the primary reformer (tube-side kinetics, heat flux limits), high- and low-temperature WGS reactors, CO₂ removal, methanation, and the Haber-Bosch synthesis loop with compression train. Full molar flow balances and equipment sizing at each stage.

          SMR Haber-Bosch Reactor Design WGS Compression Train
          View Document
          Sulphuric Acid Regeneration Process

          Design study of a spent sulphuric acid regeneration unit. Covers the combustion furnace (air/acid feed ratios, flame temperature), catalytic SO₂→SO₃ converter with interbed cooling, oleum and final absorbers, and the waste heat recovery train. Equipment sizing and operating rationale at each section.

          Combustion SO₂/SO₃ Chemistry Catalytic Converter Absorption Heat Recovery
          View Document

          Notes & Problem Sets

          Raw chapter notes from Perry's and worked problem sets from LearnChemE and YouTube lecture series.

          › Perry's Reference Notes 7 notes
          ⚙️
          Pumps
          Perry's Ch. 10 — centrifugal and positive displacement pump selection, NPSH, affinity laws, system curve.
          Open Notes →
          🔩
          Compressors
          Perry's Ch. 10 — reciprocating and centrifugal compressor thermodynamics, intercooling, capacity control.
          Open Notes →
          🔥
          Heat Transfer
          Perry's Ch. 11 — conduction, convection, radiation, LMTD/NTU, shell-and-tube and air-cooled design.
          Open Notes →
          💧
          Fluid Dynamics
          Perry's Ch. 6 — pipe friction, two-phase flow, pressure drop through fittings, flow regime maps.
          Open Notes →
          🌡️
          Thermodynamics
          Perry's Ch. 4 — equation of state, fugacity, phase equilibria, excess properties, departure functions.
          Open Notes →
          ⚠️
          Process Safety
          Perry's + CCPS — consequence modeling, dispersion, fire and explosion, toxic exposure estimation.
          Open Notes →
          🧪
          Mass Transfer
          Perry's — absorption, stripping, and interphase mass-transfer fundamentals.
          Open Notes →
          › Problem Sets 5 sets
          🔥
          LearnChemE — Heat Transfer
          CU Boulder — conduction, convection, heat exchanger design, and radiation.
          Open Problem Set →
          🌡️
          LearnChemE — Thermodynamics
          CU Boulder — EOS applications, phase diagrams, and mixture thermodynamics.
          Open Problem Set →
          ⚗️
          YT — Kinetics & Thermodynamics
          Rate laws, Arrhenius, activation energy, and equilibrium — hand-worked.
          Open Problem Set →
          🧫
          YT — Separations
          Distillation, absorption, extraction, and membrane separations — hand-worked solutions.
          Open Problem Set →
          🌊
          YT — Fluid Dynamics
          Pipe flow, pumping systems, compressible flow, and non-Newtonian flow — hand-worked solutions.
          Open Problem Set →

          Primary References

          › Technical Library 13 books
          Perry's Chemical Engineers' Handbook Guidelines for Engineering Design for Process Safety Layer of Protection Analysis Applied Process Design for Chemical and Petrochemical Plants Chemical Engineering Design Chemical Engineers' Condensed Encyclopedia of Process Equipment Oxford Dictionary of Chemical Engineering Product and Process Design Principles Guidelines for Pressure Relief and Effluent Handling Systems Handbook for Petrochemical Processes Plant Design and Economics for Chemical Engineers Guidelines for Hazard Evaluation Procedures Ethylene: A Keystone to the Petrochemical Industry

          Thermodynamics & Process Design — Worked Problems

          72 hand-worked problems recorded as instructional walkthroughs, organized by playlist. Click any thumbnail to play.

          › Thermodynamics — Worked Problems 52 videos
          Thermicity vs Temperature: Van't Hoff Equation
          6:00
          Heterogeneous Reaction Equilibrium
          16:28
          Van't Hoff Equation
          10:20
          Reaction Equilibrium — Inert Addition
          4:44
          Reaction Equilibrium — Pressure Dependence
          3:17
          Azeotrope Identification
          11:35
          Liquid-Liquid Extraction — Ternary Phase Diagrams
          5:11
          Solid-Solid-Liquid Phase Equilibria Diagram
          5:25
          Immiscible Liquids — Phase Recognition
          7:17
          Immiscible Liquids
          5:42
          LLE Partially Miscible Liquids — Conceptual
          5:23
          Gibbs Free Energy of Mixing — Qualitative
          3:45
          Gibbs Free Energy of Mixing — Phase Separation
          11:15
          LLE vs Temperature (Gibbs Free Energy)
          7:54
          Gibbs Free Energy (Mixing)
          6:00
          Cubic EOS — Conceptual
          2:01
          Heat of Mixing / Raoult's Law Deviations
          3:53
          Heat of Mixing
          6:35
          Henry's Law
          3:19
          Henry's Law — Stripper
          18:35
          Osmosis (Fugacity) — Part 2
          4:08
          Osmosis (Fugacity)
          13:37
          Non-Ideal Solutions: Activity Coefficients
          9:36
          Chemical Potential — Solubility
          5:38
          Chemical Potential — Qualitative
          10:21
          Fugacity — Two Components, Non-ideal Solution
          6:15
          Fugacity Coefficient — Vapor (Single Component)
          6:34
          Clausius-Clapeyron: Boiling Point Estimation
          5:03
          Heat of Vaporization — Clapeyron Equation
          7:17
          Clapeyron Equation Graph
          3:08
          Entropy Departure Function
          7:46
          Molecular Attractive & Repulsive Forces
          5:05
          Pressure-Enthalpy Diagram — Throttle
          2:24
          Enthalpy vs Entropy Graph — VLE Envelope
          9:06
          Single Component Phase Equilibrium
          3:16
          Linde Liquefaction — Yield
          6:50
          Linde Liquefaction: Joule-Thompson Throttle
          10:32
          Maxwell Relations
          8:19
          Joule-Thompson Effect (Throttling)
          13:54
          Refrigeration Cycle — Irreversible
          23:23
          Rankine Cycle Efficiency
          5:56
          Adiabatic Turbine
          5:10
          Irreversible Compressor Efficiency
          9:09
          Reversible vs Irreversible Compression
          20:58
          Irreversible & Reversible Turbine Work
          17:48
          Turbine Expander Efficiency
          9:56
          Comparing Flame Temperatures — Different Oxidizers (2/2)
          7:45
          Comparing Flame Temperatures — Different Oxidizers (1/2)
          3:12
          Heat of Reaction from Heat of Formations
          12:11
          Adiabatic Expansion of Liquid — Conceptual
          13:34
          Isothermal vs Adiabatic: Equilibrium Conversion
           
          Heat of Reaction - Temperature Dependence (Kirchhoff's Law)
           
          › Process Design — Seader Textbook 9 videos
          Number of Stages: Fenske Method
          9:58
          Absorber-Kremser-Design (Hydrocarbon System)
          16:23
          Heat Integration Evaluation
          14:37
          Distillation Tower Reboiler Required Area (Steam Service)
          4:28
          Shell and Tube Exchanger Configuration Selection
          6:31
          Heat Exchanger Duties and Cooling Curves
          8:50
          Turbine Shaft Work
          8:42
          Heat Exchanger Simulation Walkthrough
          10:53
          Pumping Liquid: Power and Thermodynamic Coefficient
          5:49
          › Design Problems — Peters Textbook 11 videos
          Finned Double Pipe Exchanger Area
          9:06
          Heat Exchanger Selection
          4:06
          Tube-side Heat Transfer and Pressure Drop Correlations
          3:42
          Heat Exchanger Area Calculation: Segmented
          8:32
          Heat Exchanger Thermal Driving Force Correction Factors (F)
          2:48
          Rotary Vacuum Filter
          9:55
          Liquid Filtration Scale-up
          5:36
          Dryer Selection
          5:53
          Adsorber Scale-up
          9:22
          Gas Membrane Separation
          8:40
          Adsorbent Loading
          4:32
          Joshua_Sharpes_Resume.pdf